課程資訊
課程名稱
 光電高分子科技專論
Special Topics in Electro-optic Polymers 
開課學期
 100-2 
授課對象
 學程  光電科技學程  
授課教師
 鄭如忠 
課號
 PSE7017 
課程識別碼
 549 M4010 
班次
  
學分
 3 
全/半年
 半年 
必/選修
 選修 
上課時間
 星期五2,3,4(9:10~12:10) 
上課地點
 共309 
備註
 總人數上限：48人 
Ceiba 課程網頁
 http://ceiba.ntu.edu.tw/1002PSE7017 
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課程概述

This course comprises the following chapters:
Chap. 1. Introduction
Chap. 2. Nonlinear Optics
Chap. 3. Liquid Crystals
Chap. 4. OLEDs and PLEDs
Chap. 5. Polymer Solar Cells
Chap. 6. Other Relevant Fields 

課程目標
 Opto-electronic polymers have become omnipresent in our daily lives. Particularly, the flat panel display and advanced energy generation technologies, have made remarkable gains in recent years. This course attempts to expound the field in a manner that the students will be able to understand, such as why a given product operates in a certain way and what are the reasons for using polymeric materials to fabricate opto-electronic devices.  
課程要求
 Prior experiences with Polymer Chemisry and Physics 
預期每週課後學習時數
  
Office Hours
 備註： Tue.: 2-3 p.m. Thur.: 2-3 p.m. 
指定閱讀
 Lecture notes will be provided. 
參考書目
 1. "Polymers for Second-Order Nonlinear Optics", edited by G. A. Lindsay and K. D. Singer, ACS, Washighton, DC 1995.

2. C. C. Chang, et al. “Polymers for Electro-Optical Modulation”, J. Macro. Sci., Polym. Reviews, 45 (2005) 125-170.

3. Y. J. Cheng et al. "Synthesis of Conjugated Polymers for Organic Solar Cell Applications", Chem. Rev., 2009, 109 (11), pp 5868–5923
 
評量方式
(僅供參考)
    
課程進度
週次
日期
單元主題
第1週
 2/24  syllabus and brief introduction of optoelectronic polymers. 
第2週
 3/02  Chap. 1. Introduction of opto-electronics
Chap. 2. Nonlinear Optics-Pockels effect, EO modulator  
第3週
 3/09  Continue on Chap.2. Nonlinear Optics: guest-host system, side-chain system, main-chain system, and crosslinked system; in situ poling, order parameter, cut-off wavelength, resonance enhancement, first hyperpolarizability, thermal degradation of chromophores, high Tg Polyimide. 
第4週
 3/16  Continue on Chap. 2 Nonlinear Optics: side-chain system, main-chain sytstem, and crosslinked system: photocrosslinked system--the fatal issue: photodegradation of NLO chromophore; thermal fluctuation leads to poor poling efficiency; a detrimental point of thermally crosslinked system: ununiform crosslinking density; sol-gel materials with poor waveguide properties: heteregeneous components (organic/inorganic); pop quiz 1: what is order parameter? 
第5週
 3/23  Continue on Chap. 2 Nonlinear Optics: crosslinked systmem: lattice hardening system; the difference between hybrid ande composite; organic sol-gel materials; all sol-gel organic/inorganic materials, dendrimer system, and self-assembly system, lattice-hardening system; pop quiz 2: pros and cons of side-chain and main-chain system.  
第6週
 3/30  lambda-shaped chromohores, their guest-host system, and main-chain PU system; pop quiz 3: pros and cons of NLO crosslinked system 
第7週
 4/06  spring break 
第8週
 4/13 
Thermally stable NLO materials via sol-gel process: sol-gel reaction, organic-inorganic system, polyimide/inorganic system, all organic sol-gel system, nanocomposite system, semi-IPN system, full IPN system, and hybrid system; pop quiz: the choice of fundmental wavelength when taking UV-vis absorption behavior into account.
 
第9週
 4/20  mid-term 
第10週
 4/27  Orderly arranged NLO materials based on chromophore-containing dendrons on exfoliated layered templates.
 
第11週
 5/04  Synthesis of Dendrons with Two Alternating Peripheral Functional Groups
and Their Applications in Electro-Optics;Thermally Stable NLO Polymers via Sequential Self-Repetitive Reaction(SSRR)
 
第12週
 5/11  leave of absence 
第13週
 5/18  continue on Thermally Stable NLO Polymers via Sequential Self-Repetitive Reaction(SSRR); NLO Papers Illustrated As Individual Examples for Research 
第14週
 5/25  Introduction to OLEDs: theory of photoluminescence and electroluminescence; stoke shift and anti-stoke shift; HOMO, LUMO and energy gap. 
第15週
 6/01  eternal quantum yield and internal quantum yield; hole and electron transport; charge mobility, time of flight methold; energy transfer: Förster Energy Transfer, Dexter Engergy Transfer, guest emitter, host emitter. 
第16週
 6/08  CIEx,y 1931; degree of colorfulness; color gamut; Luminance Efficiency (cd/A); Power Efficiency (lm/W); I-V-L characteristics of the OEL device.
 
第17週
 6/15  Charge Injection and Transporting Materials: configuration of OLEDs, hole transport layer (materials), electron transport layer (materials), emitting layer (materials).